Don't give in whenever they throw tantrums. Sit down & plan a time-table together. Be firm that screen time is limited daily & only given after work is completed. Always try to catch him doing right things, eg. if he finishes his homework or play well with sister, give affirmation.
Never punish or worse, hit our kids when we are "boiling" ourselves. I do cane once in a while for more serious acts of defiance but I use it only after I have calmed down & could explain to them the reason why the act warrants caning. Always try to remind myself the child always learn more from our acts as role model. If we shout a lot, why can't they shout at home too?
MIL issue is the hardest. We can't control how they respond to our kids & sometimes, hard to convince them to do things our way without offending them. Have you considered putting him in student care after school? I think better than watching TV all day long.
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