Typically, babies can master the straw cups by the time they turn 15 months. My favourite straw cup is Tommee Tippee Explora straw cup. I generally love Tommee Tippee stuff because of their design and reliability.
Here's an article that reviews and rates the best straw cups there are out there. Hopefully this will help:
http://www.popsugar.com/moms/Reviews-Straw-Sippy-Cups-11918492
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